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Oral presentation

Effects of sulfide ions on the cathodic polarization behavior of copper electrodes in compacted bentonite

Kitayama, Ayami; Nagata, Shuhei*; Inoue, Hiroyuki*; Dobashi, Ryuta*

no journal, , 

no abstracts in English

Oral presentation

Estimation of the concentration of hydrogen peroxide produced by radiolysis of aqueous solutions containing ferrous compounds

Hata, Kuniki; Sato, Tomonori; Inoue, Hiroyuki*; Taguchi, Mitsumasa*; Seito, Hajime*; Kaji, Yoshiyuki

no journal, , 

no abstracts in English

Oral presentation

Calculation of corrosion environment using corrosion database under irradiation

Sato, Tomonori; Hata, Kuniki; Kaji, Yoshiyuki; Inoue, Hiroyuki*; Taguchi, Mitsumasa*; Seito, Hajime*; Tada, Eiji*; Abe, Hiroshi*; Akiyama, Eiji*

no journal, , 

Water radiolysis calculations were performed to evaluate corrosion environments under irradiation by using database of corrosion under irradiation. It was confirmed that the dissolved oxygen is one of major factors to determine the generation of hydrogen peroxide, and the concentration of hydrogen peroxide could be controlled by the control of dissolved oxygen concentration. As a result of the calculation for the water radiolysis including impurities, the effects of Cl$$^{-}$$ on water radiolysis is negligible at concentration less than 10$$^{-3}$$mol/L. The effects of Br$$^{-}$$ is negligible at concentration less than 10$$^{-6}$$mol/L. The effects of HCO$$_{3}$$$$^{-}$$ is negligible at concentration less than 10$$^{-2}$$mol/L.

Oral presentation

Effect of oxygen concentration on the corrosion rate of carbon steel under air/solution alternating condition

Otani, Kyohei; Tsukada, Takashi; Ueno, Fumiyoshi; Kato, Chiaki

no journal, , 

It was reported that the corrosion rate of carbon steel was accelerated under the air/solution alternating condition. In this presentation, it is investigated that the effect of oxygen concentration on the corrosion rate of steel under the air/solution alternating condition. As a result, the corrosion rate of carbon steel under the air/solution alternating condition did not increase linearly with increasing oxygen concentration in the air, and the slope in the low concentration range (0-5%) is greater than in the high concentration range (5-20.8%). This suggests that the corrosion rate may be accelerated around the air/solution interface on the inner surface of the PCV if even a small amount of oxygen is introduced into the PCV during the debris removal process.

Oral presentation

Mechanism of localized corrosion in crevice of stainless steel in high temperature and high purity water

Soma, Yasutaka

no journal, , 

Commemorative speech for "The Award of JSCE for young researcher" of Japan Society of Corrosion Engineering on May 21st 2020, entitled "Characterization of the mechanism of localized corrosion in the crevices of stainless steel in high-temperature, high-purity water" will be made. In this study, we conducted followings: (i) Corrosion test of Type 316L stainless steel to analyze susceptibility to localized corrosion within a crevice in 561K high purity water, and (ii) Develop a sensor system to measure the solution conductivity in a crevice and study relationship between crevice water chemistry and the localized corrosion. These studies were done for the purpose of clarifying the mechanism of stress corrosion cracking (SCC). It was shown that Type-316L stainless steel is susceptible to intergranular corrosion inside the crevice. The developed sensors detected very high solution conductivity in the vicinity of the intergranular corroded area indicate highly corrosive environments were formed in crevice with small gaps. This system can be applied to clarify the mechanism of corrosion related failure, such as SCC, and is expected to contribute to the safety improvement of nuclear reactors.

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